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【GIA 2023 冬季】綠柱石的微觀世界 上

 寶石學(xué)讀書會 2024-03-16 發(fā)布于陜西

寫在前面:方便同學(xué)們學(xué)習(xí),今天開始發(fā)布的文章均為中英文對照,,希望對大家有所幫助。

The beryl group of beryllium silicate minerals currently contains six member species, all of which have a hexagonal crystal structure: beryl, pezzottaite, bazzite, avdeevite, stoppaniite, and the most recent member, johnkoivulaite, which was named as a new mineral in 2019 after GIA’s analytical microscopist, John Koivula. As faceted gems, beryl and pezzottaite are the most commonly encountered species. Beryl is the most common beryllium-containing mineral and often forms in pegmatitic environments or as a product of metasomatism. Also possible is a unique set of conditions in which beryl can crystallize from magma-derived gases and groundwater, as in the case of the red beryl deposit in the state of Utah. Beryl gems include blue aquamarine), golden beryl, red beryl, pink morganite, colorless goshenite, as well as Maxixe beryl, which is commonly dark blue with an unstable color. Emerald is the green variety of beryl colored by chromium and/or vanadium. Pezzottaite was first discovered in a granitic pegmatite in Madagascar in 2002 . This unique bright pink beryl mineral has high cesium and lithium contents, which differentiate it as a unique beryl-group mineral.

Be硅酸鹽綠柱石族礦物含有六個(gè)礦物種,均具有六方晶系晶體結(jié)構(gòu),,分別為綠柱石,、pezzottaite銫柱石(化學(xué)式為Cs(Be2Li)Al2Si6O18)、bazzite鈧柱石(化學(xué)式為Be3(Sc,Al)2Si6O18),、avdeevite(以Na為主的堿性綠柱石),、stoppaniite[化學(xué)式為(Fe,Al,Mg)4(Be6Si12O36)*(H2O)2(Na,□),發(fā)現(xiàn)于意大利],,以及2019年最近發(fā)現(xiàn)的新成員johnkoivulaite[化學(xué)式為Cs(Be2B)Mg2Si6O18,,發(fā)現(xiàn)于緬甸抹谷寶石礦區(qū)]。作為一種刻面型寶石,,綠柱石族礦物中綠柱石和銫柱石最為常見,,其中綠柱石是最常見的含鈹?shù)V物,通常形成于偉晶環(huán)境,,或作為一種交代作用的產(chǎn)物,,也可作為一種地質(zhì)構(gòu)造的特征礦物,在這種環(huán)境下,,綠柱石結(jié)晶于巖漿成因的氣體和地下水中,例如猶他州的紅色綠柱石礦床,。綠柱石寶石包括藍(lán)色的海藍(lán)寶石,、金綠柱石、紅色綠柱石,、粉色摩根石,、無色綠柱石、深藍(lán)色的馬希謝綠柱石(顏色不穩(wěn)定),、綠色的祖母綠(由Cr或V致色),。2002年,在馬達(dá)加斯加首次發(fā)現(xiàn)銫柱石(Pezzottaite),,呈現(xiàn)特有的亮粉色,,具有高Cs、高Li的特征,,使得它成為綠柱石礦物族中的獨(dú)立礦物,。

Many of the beryl examples in the accompanying wall chart crystallized from a pegmatitic environment in which there is a high enough beryllium concentration for these gems to crystallize, which require the element as it is a bulk part of the crystal structure. These pegmatitic environments often contain fluids that get trapped along with other pegmatitic minerals, leaving a signature of their geologic formation within the gem’s interior. The minerals most likely to be observed in these pegmatitic gems include albite, apatite, muscovite, garnet, tourmaline, and quartz (Gübelin and Koivula, 1986), while rare minerals such as stibiotantalite and monazite are only occasionally encountered.

集中很多綠柱石的例子均形成于偉晶環(huán)境,由于Be是組成晶體結(jié)構(gòu)的主要組成,,而這種環(huán)境中具有足夠高的Be,,足以使這類寶石發(fā)生結(jié)晶,。偉晶環(huán)境中通常含有流體,可被其他偉晶礦物捕獲,,形成保留地質(zhì)信息的內(nèi)部特征,。在這些偉晶礦物中最常見到的礦物包裹體包括鈉長石、磷灰石,、白云母,、石榴石、電氣石和石英,,但是,,偶爾可見一些稀有礦物,如鉭銻礦,、獨(dú)居石等,。

This chart will focus on the members of the beryl group commonly seen as gems but will exclude emerald, which already has its own inclusions chart. While synthetic and treated beryl gems do exist, they are relatively uncommon, so this chart only deals with natural beryl. These include fluids and solid minerals, as well as surface features and structural inclusions. As with past charts, the images presented are not meant to be all-encompassing but offer a wide range of the possible types of inclusions found in beryl gems.

本圖集中專注視作寶石的綠柱石族成員,但不包括祖母綠(已有自己獨(dú)立的圖集),,雖然合成和優(yōu)化處理綠柱石確實(shí)存在,,但相對不常見。因此本圖集僅涉及天然綠柱石族礦物,。包括流體包裹體,、固相礦物包裹體以及表面特征和結(jié)構(gòu)特征等。與過去的圖集相同,,所呈現(xiàn)的圖集并不意味著涵蓋所有,,但提供了綠柱石族寶石中廣泛發(fā)現(xiàn)的可能存在的內(nèi)含物類型。

This 9.885 kg specimen of aquamarine on albite with a quartz cathedral center, measuring 31 × 23 × 28 cm, is from Pakistan’s Shigar Valley. Courtesy of GIA Museum, collection no. 43068. Photo by Robert Weldon.

樣品重9.885公斤,,尺寸為31 × 23 × 28 cm,,產(chǎn)自巴基斯坦Shigar谷,海藍(lán)寶石與石英和鈉長石共生,。收藏于GIA博物館,,編號43068。攝影:Robert Weldon

This aquamarine has been significantly etched, resulting in a cave-like cavity filled with sharp spires of beryl. Field of view 3.28 mm.
這顆海藍(lán)寶石經(jīng)歷過明顯的溶蝕作用,,使其內(nèi)部形成了一個(gè)空穴,,內(nèi)部充填了綠柱石的錐狀物。視域3.28mm,。
A complex fluid inclusion and etch ribbons are present in this morganite from Minas Gerais, Brazil. Field of view 2.78 mm.
產(chǎn)自巴西米納斯吉拉斯州摩根石,,其中可見復(fù)雜的立體包裹體和蝕刻帶狀物。視域2.78mm,。
Hexagonal growth zoning in this aquamarine from Brazil is revealed using polarized light. Field of view 15.67 mm.
產(chǎn)自巴西的海藍(lán)寶石,,正交偏光鏡下可見明顯的六邊形色帶。視域15.67mm
A rare inclusion of beryl is preserved in this fluorite crystal from Inyo, California. Field of view 8.6 mm.
螢石晶體中罕見的綠柱石包裹體,,樣品產(chǎn)自加利福尼亞Inyo礦區(qū),,視域8.6mm。
Skeletal dendritic inclusions of ilmenite are the cause of silvery aventurescence in this aquamarine from Brazil. Field of view 2.59 mm.
海藍(lán)寶石中樹枝狀鈦鐵礦包裹體,,是其產(chǎn)生砂金效應(yīng)的原因,。視域2.59mm
This morganite crystal shows a heart-shaped etch feature on the pinacoid face, as seen using differential interference contrast microscopy. Field of view 1.5 mm.
利用微分干涉差顯微鏡觀察,,可見摩根石晶體中具有一個(gè)心形的蝕刻特征,。視域1.5mm。
A goshenite beryl from Pakistan is host to pinkish orange crystals of the rare mineral zwieselite. Field of view 7.61 mm.
產(chǎn)自巴基斯坦的無色綠柱石,,其中可見粉橙色晶體,,為罕見的氟磷鐵石(zwieselite)
Galenobismutite was identified in the rare beryl-group mineral pezzottaite. Field of view 0.91 mm.
銫柱石中的輝鉛鉍礦。視域0.91mm,。
Transparent green crystals of monazite along with black ferrocolumbite crystals are seen in this goshenite from Pakistan. Field of view 4.49 mm.
產(chǎn)自巴基斯坦的無色綠柱石,,內(nèi)部可見透明的綠色獨(dú)居石 晶體,伴生黑色鈮鐵礦,。視域4.49mm,。

This complex fluid inclusion in beryl, which resembles an eagle’s head, contains a liquid, gas, and numerous solid crystals that show birefringence using polarized light. Field of view 3.55 mm.
綠柱石中復(fù)雜的流體包裹體,其形態(tài)類似于鷹頭,,正交偏光鏡下觀察可見內(nèi)部氣相,、液相和多個(gè)固相晶體包裹體。

A fluid-filled, three-phase inclusion in beryl showing thin-film interference under oblique fiber-optic lighting. Field of view 3.52 mm.
使用斜向光纖照明法,,叫可見綠柱石中充滿液體的三相包裹體所形成的薄膜干涉,。視域3.52mm
This aquamarine from Brazil contains planes of numerous fluid inclusions that show a “bubble in bubble” effect resulting from the immiscibility of an aqueous liquid and carbon dioxide liquid and gas phases. Field of view 1.79 mm.
產(chǎn)自巴西的海藍(lán)寶石,,可見大量的流體包裹體,,其內(nèi)部為不混溶的液態(tài)水、液態(tài)二氧化碳和氣相二氧化碳,,呈現(xiàn)出“氣泡中的氣泡”的效果。視域1.79mm,。
A euhedral crystal of kunzite is preserved in this morganite from Minas Gerais, Brazil. Field of view 8.81 mm.
產(chǎn)自巴西米納斯吉拉斯州的摩根石,,其內(nèi)部可見自形的紫鋰輝石。視域8.81mm,。
Small blue crystals of gahnite are observed in this cat’s-eye heliodor reportedly from Brazil. Field of view 1.10 mm.
樣品為產(chǎn)自巴西的金綠柱石貓眼,,可見小的藍(lán)色鋅尖晶石晶體。視域1.10mm,。

Etch features containing yellow epigenetic limonite are present in this rare example of johnkoivulaite, recognized as a beryl-group mineral in 2019. Field of view 1.88 mm.
罕見的johnkoivulaite,,2019年被認(rèn)為屬于綠柱石族。其內(nèi)部可見含有黃色的后生褐鐵礦包裹體的蝕刻特征。視域1.88mm,。

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